Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

Qu'est-ce que Menthol ?

Menthol est un composé chimique enregistré sous le numéro CAS 2216-51-5. Formule brute: C10H20O. Masse molaire: 156.26 g/mol. IUPAC: (1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-ol.

Quel est le numéro CAS de Menthol ?

Le numéro CAS de Menthol est 2216-51-5 — un identifiant unique du Chemical Abstracts Service (CAS).

Quelle est la formule brute de Menthol ?

Formule brute: C10H20O. Masse molaire: 156.26 g/mol. logP (XLogP3): 3. PSA: 20.2 Å².

Quels sont les dangers GHS de Menthol ?

Selon la classification GHS, Menthol doit porter les mentions de danger suivantes : H315 (Provoque une irritation cutanée.), H320 (Provoque une irritation des yeux.), H336 (Peut provoquer somnolence ou vertiges.), H402 (Działa szkodliwie na organizmy wodne).

Où acheter Menthol ?

Menthol est disponible dans notre boutique. Voir le produit : https://epchems.online/products/l-menthol/

D'où proviennent les données chimiques de Menthol ?

Les données chimiques de Menthol proviennent de sources faisant autorité : PubChem (NIH), ChEMBL (EBI). PubChem CID: 16666. Conformes au règlement CLP (CE 1272/2008), disponibles sous licence CC-BY 4.0.

Menthol

(-)-Menthol

CAS 2216-51-5 · C₁₀H₂₀O · MW 156.26 g/mol

À propos de Menthol

Menthol est un composé chimique enregistré sous le numéro CAS 2216-51-5, de formule brute C₁₀H₂₀O, et de masse molaire 156.26 g/mol.

La molécule contient 31 atomes reliés par 31 liaisons chimiques. Le nom systématique IUPAC complet de ce composé est (1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-ol. Le modèle 3D interactif ci-dessus permet de visualiser l'arrangement spatial des atomes — vous pouvez le faire pivoter à la souris, zoomer avec la molette et basculer entre les modes de visualisation squelette / Ball & Stick / Space Fill.

Du point de vue des propriétés physico-chimiques, le coefficient de partage logP = 3 (valeur positive, composé lipophile), surface polaire PSA = 20.2 Å², 1 donneurs et 1 accepteurs de liaisons hydrogène. Ces paramètres sont essentiels pour évaluer la biodisponibilité et l'interaction avec les biomolécules.

Les données chimiques de ce composé proviennent de PubChem (NIH NLM NCBI), l'une des plus grandes bases de données chimiques au monde. Toutes les informations sont mises à jour automatiquement et enrichies de traductions des mentions de danger GHS conformes au règlement CLP (CE 1272/2008). Le widget ci-dessus peut être utilisé à des fins éducatives, de recherche et commerciales.

Propriétés physico-chimiques

Wzór sumaryczny	C₁₀H₂₀O
Masa molowa	156.26 g/mol
IUPAC	(1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-ol
SMILES	`C[C@@H]1CC[C@H]([C@@H](C1)O)C(C)C`
InChIKey	`NOOLISFMXDJSKH-KXUCPTDWSA-N`
logP (XLogP3)	3
PSA	20.2 Å²
HBD / HBA	1 / 1
PubChem CID	CID 16666 ↗

Sécurité GHS

Sygnał: Uwaga

GHS07

H315 — Działa drażniąco na skórę

H320 — H320

H336 — Może wywoływać uczucie senności lub zawroty głowy

H402 — Działa szkodliwie na organizmy wodne

Littérature scientifique

Literatura naukowa

2 artykułów · 1 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

🔓

Nematicidal activity of menthol and its dithiophosphoric derivatives

Georgiy Shumatbaev, Anastasia Egorova, Alsu Gatiyatullina et al. (2021) · EDP Sciences

Open AccessDOI ↗PDF ↗

Nematicidal activity of menthol and its dithiophosphoric derivatives

Gatiyatullina A., Shumatbaev G., Nikitin E. et al. (2021)

$ Paywall

Dane z PubMed (NIH NLM), OpenAlex (CC0), Semantic Scholar (AI2). AI Summary wygenerowane przez Semantic Scholar TLDR. Artykuły z ikoną wymagają płatnego dostępu.

Synonymes

l-Menthol · (-)-menthol · 2216-51-5 · Levomenthol · l-(-)-Menthol · (-)-Menthyl alcohol · Levomentholum · U.S.P. Menthol · (1R)-(-)-Menthol · (-)-(1R,3R,4S)-Menthol · D-(-)-Menthol · (-)-trans-p-Menthan-cis-ol · levomentol · (1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexan-1-ol · Menthol, (1R,3R,4S)-(-)-

Sources des données

📊 PubChem CID 16666 — NIH
🔬 NIST WebBook — spektroskopia
🌐 Wikidata
💊 ChEMBL — bioaktywność

Acheter en boutique

L-Menthol →

Molécules apparentées

1-Hexanol CAS 111-27-3 · C6H14O Cyclohexanone CAS 108-94-1 · C6H10O Glycerol CAS 56-81-5 · C3H8O3 Trichloroethylene CAS 127-18-4 · C2Cl4 L-Lysine CAS 56-87-1 · C6H14N2O2 Dimethylformamide CAS 68-12-2 · C3H7NO