Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

Musk Pure ist eine chemische Verbindung, registriert unter der CAS-Nummer 1222-05-5. Summenformel: C18H26O. Molmasse: 258.4 g/mol. IUPAC: 4,6,6,7,8,8-hexamethyl-1,3,4,7-tetrahydrocyclopenta[g]isochromene.

Wie lautet die CAS-Nummer von Musk Pure?

Die CAS-Nummer von Musk Pure ist 1222-05-5 — eine eindeutige Kennung des Chemical Abstracts Service (CAS).

Wie lautet die Summenformel von Musk Pure?

Summenformel: C18H26O. Molmasse: 258.4 g/mol. logP (XLogP3): 4.8. PSA: 9.2 Å².

Welche GHS-Gefahren hat Musk Pure?

Gemäß der GHS-Klassifizierung muss Musk Pure mit den folgenden Gefahrenhinweisen gekennzeichnet werden: H400 (Sehr giftig für Wasserorganismen.), H410 (Sehr giftig für Wasserorganismen mit langfristiger Wirkung.).

Wo kann ich Musk Pure kaufen?

Musk Pure ist in unserem Shop erhältlich. Produkt ansehen: https://epchems.online/products/musk-pure/

Woher stammen die chemischen Daten für Musk Pure?

Die chemischen Daten für Musk Pure stammen aus zuverlässigen Quellen: PubChem (NIH), ChEMBL (EBI). PubChem CID: 91497. Konform mit der CLP-Verordnung (EG 1272/2008), verfügbar unter der Lizenz CC-BY 4.0.

Musk Pure

Galaxolide

CAS 1222-05-5 · C₁₈H₂₆O · MW 258.4 g/mol

Über Musk Pure

Musk Pure ist eine chemische Verbindung, registriert unter der Nummer CAS 1222-05-5, mit der Summenformel C₁₈H₂₆O, und einer Molmasse von 258.4 g/mol.

Das Molekül enthält 45 Atome, verbunden durch 47 chemische Bindungen. Der vollständige systematische IUPAC-Name dieser Verbindung lautet 4,6,6,7,8,8-hexamethyl-1,3,4,7-tetrahydrocyclopenta[g]isochromene. Das interaktive 3D-Modell oben zeigt die räumliche Anordnung der Atome — Sie können es mit der Maus drehen, mit dem Scrollrad zoomen und zwischen den Darstellungsmodi Skelett / Ball & Stick / Space Fill wechseln.

Hinsichtlich der physikalisch-chemischen Eigenschaften der Verteilungskoeffizient logP = 4.8 (positiver Wert, lipophile Verbindung), polare Oberfläche PSA = 9.2 Å², 0 Donatoren und 1 Wasserstoffbrücken-Akzeptoren. Diese Parameter sind entscheidend für die Beurteilung der Bioverfügbarkeit und der Wechselwirkung mit Biomolekülen.

Die chemischen Daten für diese Verbindung stammen aus PubChem (NIH NLM NCBI), einer der größten chemischen Datenbanken der Welt. Alle Informationen werden automatisch aktualisiert und um GHS-Gefahrenhinweise gemäß der CLP-Verordnung (EG 1272/2008) ergänzt. Das obige Widget darf für Bildungs-, Forschungs- und kommerzielle Zwecke verwendet werden.

Physikalisch-chemische Eigenschaften

Wzór sumaryczny	C₁₈H₂₆O
Masa molowa	258.4 g/mol
IUPAC	4,6,6,7,8,8-hexamethyl-1,3,4,7-tetrahydrocyclopenta[g]isochromene
SMILES	`CC1COCC2=CC3=C(C=C12)C(C(C3(C)C)C)(C)C`
InChIKey	`ONKNPOPIGWHAQC-UHFFFAOYSA-N`
logP (XLogP3)	4.8
PSA	9.2 Å²
HBD / HBA	0 / 1
PubChem CID	CID 91497 ↗

GHS-Sicherheit

Sygnał: Uwaga

GHS09

H400 — Działa bardzo toksycznie na organizmy wodne

H410 — Działa bardzo toksycznie na organizmy wodne, powodując długotrwałe skutki

Wissenschaftliche Literatur

Literatura naukowa

8 artykułów · 2 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

📈 Timeline publikacji (8 artykułów)

Wysokość słupka = liczba artykułów w roku. Hover dla szczegółów.

🔓

Galaxolide and tonalide modulate neuroendocrine activity in marine species from two taxonomic groups.

Ehiguese FO, Rodgers ML, Araújo CVM et al. (2021) · Environmental research

Open AccessDOI ↗PubMed ↗PDF ↗

🔓

Derivation of predicted no effect concentration and ecological risk assessment of polycyclic musks tonalide and galaxolide in sediment.

Li W, Wang L, Wang X et al. (2022) · Ecotoxicology and environmental safety

Open AccessDOI ↗PubMed ↗PDF ↗

Biological responses of alga Euglena gracilis to triclosan and galaxolide and the regulation of humic acid.

Ding T, Wei L, Hou Z et al. (2022) · Chemosphere

$ PaywallDOI ↗PubMed ↗

Galaxolide and Irgacure 369 are novel environmental androgens.

Li M, Wang R, Wang P (2023) · Chemosphere

$ PaywallDOI ↗PubMed ↗

Ball-milled biochar for galaxolide removal: Sorption performance and governing mechanisms.

Zhang Q, Wang J, Lyu H et al. (2019) · The Science of the total environment

$ PaywallDOI ↗PubMed ↗

Individual and combined toxicity of silver nanoparticles and triclosan or galaxolide in the freshwater algae Euglena sp.

Ding T, Wei L, Yue Z et al. (2023) · The Science of the total environment

$ PaywallDOI ↗PubMed ↗

Adverse effect of environmental androgenic compounds Galaxolide and Irgacure 369 on the male reproductive system.

Li M, Wang P (2023) · Reproductive toxicology (Elmsford, N.Y.)

$ PaywallDOI ↗PubMed ↗

Preliminary assessment of galaxolide bioaccessibility in raw and cooked FISH.

Trabalón L, Alves RN, Castro Ó et al. (2018) · Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association

$ PaywallDOI ↗PubMed ↗

Dane z PubMed (NIH NLM), OpenAlex (CC0), Semantic Scholar (AI2). AI Summary wygenerowane przez Semantic Scholar TLDR. Artykuły z ikoną wymagają płatnego dostępu.

Synonyme

Galaxolide · 1222-05-5 · Abbalide · Galoxolide · HHCB · Pearlide · Galaxolide White · hexamethylindanopyran · Cyclopenta[g]-2-benzopyran, 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl- · Hexahydrohexamethyl cyclopentabenzopyran · 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-gamma-2-benzopyran · 14170060AT · CHEBI:83784 · Hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran · 1,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethylindeno(5,6-c)pyran

Datenquellen

📊 PubChem CID 91497 — NIH
🔬 NIST WebBook — spektroskopia
🌐 Wikidata
💊 ChEMBL — bioaktywność

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