Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

什么是薄荷醇？

薄荷醇是一种化学品，CAS 登记号为 2216-51-5。分子式: C10H20O. 摩尔质量: 156.26 g/mol. IUPAC: (1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-ol.

薄荷醇的 CAS 号是多少？

薄荷醇的 CAS 号为 2216-51-5——化学文摘社 (CAS) 的唯一标识符。

薄荷醇的分子式是什么？

分子式: C10H20O. 摩尔质量: 156.26 g/mol. logP (XLogP3): 3. PSA: 20.2 Å².

薄荷醇有哪些 GHS 危害？

根据 GHS 分类，薄荷醇须标注以下危险说明： H315 (造成皮肤刺激), H320 (造成眼刺激), H336 (可引起昏睡或眩晕), H402 (对水生生物有害).

在哪里可以购买薄荷醇？

薄荷醇在我们的商店有售。查看产品：https://epchems.online/products/l-menthol/

薄荷醇的化学数据来自哪里？

薄荷醇的化学数据来自权威来源：PubChem (NIH), ChEMBL (EBI)。 PubChem CID: 16666. 符合 CLP 法规（EC 1272/2008），依据 CC-BY 4.0 许可提供。

薄荷醇

(-)-Menthol

CAS 2216-51-5 · C₁₀H₂₀O · MW 156.26 g/mol

关于薄荷醇

薄荷醇 是一种化学品，登记号为 CAS 2216-51-5，分子式为 C₁₀H₂₀O，摩尔质量为 156.26 g/mol。

该分子包含 31 个原子，通过 31 个化学键连接。该化合物的完整系统 IUPAC 名称为 (1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-ol。上方的交互式 3D 模型可查看原子的空间排列——您可以用鼠标旋转、用滚轮缩放，并在骨架 / 球棍 (Ball & Stick) / 空间填充 (Space Fill) 显示模式之间切换。

在理化性质方面，分配系数 logP = 3 (正值，亲脂性化合物)，极性表面积 PSA = 20.2 Å²，1 个氢键供体和 1 个氢键受体。这些参数对于评估生物利用度以及与生物分子的相互作用至关重要。

该化合物的化学数据来自 PubChem（NIH NLM NCBI），全球最大的化学数据库之一。所有信息均自动更新，并附有符合 CLP 法规（EC 1272/2008）的 GHS 危险说明翻译。上方的小部件可用于教育、研究和商业用途。

理化性质

Wzór sumaryczny	C₁₀H₂₀O
Masa molowa	156.26 g/mol
IUPAC	(1R,2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-ol
SMILES	`C[C@@H]1CC[C@H]([C@@H](C1)O)C(C)C`
InChIKey	`NOOLISFMXDJSKH-KXUCPTDWSA-N`
logP (XLogP3)	3
PSA	20.2 Å²
HBD / HBA	1 / 1
PubChem CID	CID 16666 ↗

GHS 安全

Sygnał: Uwaga

GHS07

H315 — Działa drażniąco na skórę

H320 — H320

H336 — Może wywoływać uczucie senności lub zawroty głowy

H402 — Działa szkodliwie na organizmy wodne

科学文献

Literatura naukowa

2 artykułów · 1 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

🔓

Nematicidal activity of menthol and its dithiophosphoric derivatives

Georgiy Shumatbaev, Anastasia Egorova, Alsu Gatiyatullina et al. (2021) · EDP Sciences

Open AccessDOI ↗PDF ↗

Nematicidal activity of menthol and its dithiophosphoric derivatives

Gatiyatullina A., Shumatbaev G., Nikitin E. et al. (2021)

$ Paywall

Dane z PubMed (NIH NLM), OpenAlex (CC0), Semantic Scholar (AI2). AI Summary wygenerowane przez Semantic Scholar TLDR. Artykuły z ikoną wymagają płatnego dostępu.

同义词

l-Menthol · (-)-menthol · 2216-51-5 · Levomenthol · l-(-)-Menthol · (-)-Menthyl alcohol · Levomentholum · U.S.P. Menthol · (1R)-(-)-Menthol · (-)-(1R,3R,4S)-Menthol · D-(-)-Menthol · (-)-trans-p-Menthan-cis-ol · levomentol · (1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexan-1-ol · Menthol, (1R,3R,4S)-(-)-

数据来源

📊 PubChem CID 16666 — NIH
🔬 NIST WebBook — spektroskopia
🌐 Wikidata
💊 ChEMBL — bioaktywność

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