Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

什么是二氧化钛？

二氧化钛是一种化学品，CAS 登记号为 13463-67-7。分子式: TiO₂. 摩尔质量: 79.866 g/mol. IUPAC: dioxotitanium.

二氧化钛的 CAS 号是多少？

二氧化钛的 CAS 号为 13463-67-7——化学文摘社 (CAS) 的唯一标识符。

二氧化钛的分子式是什么？

分子式: TiO₂. 摩尔质量: 79.866 g/mol. PSA: 34.1 Å².

二氧化钛有哪些 GHS 危害？

根据 GHS 分类，二氧化钛须标注以下危险说明： H351 (怀疑会致癌(说明接触途径――如已确证无其他接触途径造成这一危害)), H319 (造成严重眼刺激), H335 (可引起呼吸道刺激), H372 (长期或反复接触会对器官造成伤害(说明已知的所有受影响器官)( 说明接触途径――如已确证无其他接触途径造成这一危害)), H413 (可能对水生生物造成长期持续有害影响).

在哪里可以购买二氧化钛？

二氧化钛在我们的商店有售。查看产品：https://epchems.online/products/titanium-dioxide/

二氧化钛的化学数据来自哪里？

二氧化钛的化学数据来自权威来源：PubChem (NIH)。 PubChem CID: 26042. 符合 CLP 法规（EC 1272/2008），依据 CC-BY 4.0 许可提供。

二氧化钛

CAS 13463-67-7 · TiO₂ · MW 79.866 g/mol

关于二氧化钛

二氧化钛 是一种化学品，登记号为 CAS 13463-67-7，分子式为 TiO₂，摩尔质量为 79.866 g/mol。

该分子包含 3 个原子，通过 2 个化学键连接。该化合物的完整系统 IUPAC 名称为 dioxotitanium。上方的交互式 3D 模型可查看原子的空间排列——您可以用鼠标旋转、用滚轮缩放，并在骨架 / 球棍 (Ball & Stick) / 空间填充 (Space Fill) 显示模式之间切换。

在理化性质方面，极性表面积 PSA = 34.1 Å²，0 个氢键供体和 2 个氢键受体。这些参数对于评估生物利用度以及与生物分子的相互作用至关重要。

该化合物的化学数据来自 PubChem（NIH NLM NCBI），全球最大的化学数据库之一。所有信息均自动更新，并附有符合 CLP 法规（EC 1272/2008）的 GHS 危险说明翻译。上方的小部件可用于教育、研究和商业用途。

理化性质

Wzór sumaryczny	TiO₂
Masa molowa	79.866 g/mol
IUPAC	dioxotitanium
SMILES	`O=[Ti]=O`
InChIKey	`GWEVSGVZZGPLCZ-UHFFFAOYSA-N`
logP (XLogP3)	—
PSA	34.1 Å²
HBD / HBA	0 / 2
PubChem CID	CID 26042 ↗

GHS 安全

Sygnał: Niebezpieczeństwo

GHS07

GHS08

H351 — Podejrzewa się, że powoduje raka

H319 — Działa drażniąco na oczy

H335 — Może powodować podrażnienie dróg oddechowych

H372 — Powoduje uszkodzenie narządów poprzez długotrwałe lub powtarzane narażenie

H413 — Może powodować długotrwałe szkodliwe skutki dla organizmów wodnych

H320 — H320

科学文献

Literatura naukowa

1 artykułów · 1 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

🔓

Safety assessment of titanium dioxide (E171) as a food additive

EFSA Panel on Food Additives and Flavourings (FAF), Maged Younes, Gabriele Aquilina et al. (2021) · EFSA Journal

Cytowania: 172Open AccessDOI ↗PDF ↗

Dane z PubMed (NIH NLM), OpenAlex (CC0), Semantic Scholar (AI2). AI Summary wygenerowane przez Semantic Scholar TLDR. Artykuły z ikoną wymagają płatnego dostępu.

同义词

TITANIUM DIOXIDE · 13463-67-7 · Titania · Titanium(IV) oxide · Titanium White · Titafrance · Titandioxid · Flamenco · Hombitan · Tiofine · Tioxide · Tipaque · Titanox · Rayox · Bayertitan A

数据来源

📊 PubChem CID 26042 — NIH
🔬 NIST WebBook — spektroskopia
🌐 Wikidata
💊 ChEMBL — bioaktywność

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