Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

什么是Triisobutyl Phosphate？

Triisobutyl Phosphate 是一种化学品，CAS 登记号为 126-71-6。分子式: C12H27O4P. 摩尔质量: 266.31 g/mol. IUPAC: tris(2-methylpropyl) phosphate.

Triisobutyl Phosphate 的 CAS 号是多少？

Triisobutyl Phosphate 的 CAS 号为 126-71-6——化学文摘社 (CAS) 的唯一标识符。

Triisobutyl Phosphate 的分子式是什么？

分子式: C12H27O4P. 摩尔质量: 266.31 g/mol. logP (XLogP3): 3.5. PSA: 44.8 Å².

Triisobutyl Phosphate 有哪些 GHS 危害？

根据 GHS 分类，Triisobutyl Phosphate 须标注以下危险说明： H317 (可能导致皮肤过敏反应).

在哪里可以购买Triisobutyl Phosphate？

Triisobutyl Phosphate 在我们的商店有售。查看产品：https://epchems.online/products/triisobutyl-phosphate/

Triisobutyl Phosphate 的化学数据来自哪里？

Triisobutyl Phosphate 的化学数据来自权威来源：PubChem (NIH), ChEMBL (EBI)。 PubChem CID: 31355. 符合 CLP 法规（EC 1272/2008），依据 CC-BY 4.0 许可提供。

Triisobutyl Phosphate

CAS 126-71-6 · C₁₂H₂₇O₄P · MW 266.31 g/mol

关于 Triisobutyl Phosphate

Triisobutyl Phosphate 是一种化学品，登记号为 CAS 126-71-6，分子式为 C₁₂H₂₇O₄P，摩尔质量为 266.31 g/mol。

该分子包含 44 个原子，通过 43 个化学键连接。该化合物的完整系统 IUPAC 名称为 tris(2-methylpropyl) phosphate。上方的交互式 3D 模型可查看原子的空间排列——您可以用鼠标旋转、用滚轮缩放，并在骨架 / 球棍 (Ball & Stick) / 空间填充 (Space Fill) 显示模式之间切换。

在理化性质方面，分配系数 logP = 3.5 (正值，亲脂性化合物)，极性表面积 PSA = 44.8 Å²，0 个氢键供体和 4 个氢键受体。这些参数对于评估生物利用度以及与生物分子的相互作用至关重要。

该化合物的化学数据来自 PubChem（NIH NLM NCBI），全球最大的化学数据库之一。所有信息均自动更新，并附有符合 CLP 法规（EC 1272/2008）的 GHS 危险说明翻译。上方的小部件可用于教育、研究和商业用途。

理化性质

Wzór sumaryczny	C₁₂H₂₇O₄P
Masa molowa	266.31 g/mol
IUPAC	tris(2-methylpropyl) phosphate
SMILES	`CC(C)COP(=O)(OCC(C)C)OCC(C)C`
InChIKey	`HRKAMJBPFPHCSD-UHFFFAOYSA-N`
logP (XLogP3)	3.5
PSA	44.8 Å²
HBD / HBA	0 / 4
PubChem CID	CID 31355 ↗

GHS 安全

Sygnał: Uwaga

GHS07

H317 — Może powodować reakcję alergiczną skóry

科学文献

Literatura naukowa

2 artykułów · 0 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

📈 Timeline publikacji (2 artykułów)

Wysokość słupka = liczba artykułów w roku. Hover dla szczegółów.

Tri-isobutylphosphate: a prenatal toxicity study in rats.

Ruckman SA, Green OP, Palmer AK et al. (1999) · Toxicology letters

$ PaywallDOI ↗PubMed ↗

ChemInform Abstract: NOVEL TRANSIENT TIN‐CENTERED RADICAL TRIS‐(2‐PHENYL‐2‐METHYLPROPYL)STANNYL

H. U. BUSCHHAUS, M. LEHNIG, W. P. NEUMANN (1977) · Chemischer Informationsdienst

$ PaywallDOI ↗

Dane z PubMed (NIH NLM), OpenAlex (CC0), Semantic Scholar (AI2). AI Summary wygenerowane przez Semantic Scholar TLDR. Artykuły z ikoną wymagają płatnego dostępu.

同义词

TRIISOBUTYL PHOSPHATE · 126-71-6 · Tri-isobutylphosphate · Phosphoric acid, tris(2-methylpropyl) ester · Phosphoric acid, triisobutyl ester · 6MKE1AR3GB · NSC-62222 · DTXCID6020698 · RefChem:190784 · 204-798-3 · tris(2-methylpropyl) phosphate · Isobutyl phosphate · tri-isobutyl phosphate · Phosphoric acid tris(2-methylpropyl) ester · MFCD00039849

数据来源

📊 PubChem CID 31355 — NIH
🔬 NIST WebBook — spektroskopia
🌐 Wikidata
💊 ChEMBL — bioaktywność

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