Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

Qu'est-ce que Acide adipique ?

Acide adipique est un composé chimique enregistré sous le numéro CAS 124-04-9. Formule brute: C6H10O4. Masse molaire: 146.14 g/mol. IUPAC: hexanedioic acid.

Quel est le numéro CAS de Acide adipique ?

Le numéro CAS de Acide adipique est 124-04-9 — un identifiant unique du Chemical Abstracts Service (CAS).

Quelle est la formule brute de Acide adipique ?

Formule brute: C6H10O4. Masse molaire: 146.14 g/mol. logP (XLogP3): 0.1. PSA: 74.6 Å².

Quels sont les dangers GHS de Acide adipique ?

Selon la classification GHS, Acide adipique doit porter les mentions de danger suivantes : H319 (Provoque une sévère irritation des yeux.).

Où acheter Acide adipique ?

Acide adipique est disponible dans notre boutique. Voir le produit : https://epchems.online/products/adipic-acid/

D'où proviennent les données chimiques de Acide adipique ?

Les données chimiques de Acide adipique proviennent de sources faisant autorité : PubChem (NIH), ChEMBL (EBI). PubChem CID: 196. Conformes au règlement CLP (CE 1272/2008), disponibles sous licence CC-BY 4.0.

Acide adipique

CAS 124-04-9 · C₆H₁₀O₄ · MW 146.14 g/mol

À propos de Acide adipique

Acide adipique est un composé chimique enregistré sous le numéro CAS 124-04-9, de formule brute C₆H₁₀O₄, et de masse molaire 146.14 g/mol.

La molécule contient 20 atomes reliés par 19 liaisons chimiques. Le nom systématique IUPAC complet de ce composé est hexanedioic acid. Le modèle 3D interactif ci-dessus permet de visualiser l'arrangement spatial des atomes — vous pouvez le faire pivoter à la souris, zoomer avec la molette et basculer entre les modes de visualisation squelette / Ball & Stick / Space Fill.

Du point de vue des propriétés physico-chimiques, le coefficient de partage logP = 0.1 (valeur positive, composé lipophile), surface polaire PSA = 74.6 Å², 2 donneurs et 4 accepteurs de liaisons hydrogène. Ces paramètres sont essentiels pour évaluer la biodisponibilité et l'interaction avec les biomolécules.

Les données chimiques de ce composé proviennent de PubChem (NIH NLM NCBI), l'une des plus grandes bases de données chimiques au monde. Toutes les informations sont mises à jour automatiquement et enrichies de traductions des mentions de danger GHS conformes au règlement CLP (CE 1272/2008). Le widget ci-dessus peut être utilisé à des fins éducatives, de recherche et commerciales.

Propriétés physico-chimiques

Wzór sumaryczny	C₆H₁₀O₄
Masa molowa	146.14 g/mol
IUPAC	hexanedioic acid
SMILES	`C(CCC(=O)O)CC(=O)O`
InChIKey	`WNLRTRBMVRJNCN-UHFFFAOYSA-N`
logP (XLogP3)	0.1
PSA	74.6 Å²
HBD / HBA	2 / 4
PubChem CID	CID 196 ↗

Sécurité GHS

Sygnał: Uwaga

GHS07

H319 — Działa drażniąco na oczy

Littérature scientifique

Literatura naukowa

20 artykułów · 4 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

📈 Timeline publikacji (20 artykułów)

Wysokość słupka = liczba artykułów w roku. Hover dla szczegółów.

Hexanedioic acid mediated surface-ligand-exchange process for transferring NaYF4:Yb/Er (or Yb/Tm) up-converting nanoparticles from hydrophobic to hydrophilic.

et al. (2009)

Cytowania: 45$ PaywallDOI ↗PubMed ↗

Continuous synthesis of organic-inorganic hybridized cubic nanoassemblies of octahedral cerium oxide nanocrystals and hexanedioic acid.

et al. (2008)

Cytowania: 10$ PaywallDOI ↗PubMed ↗

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First order temperature dependent phase transition in a monoclinic polymorph crystal of 1,6-hexanedioic Acid: an interpretation based on the landau theory approach.

(2014)

Cytowania: 1Open AccessDOI ↗PubMed ↗PDF ↗

In vivo studies on the metabolism of hexanedioic acid.

(1975)

Cytowania: 10$ PaywallDOI ↗PubMed ↗

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Urinary metabolites of cis-9,10-methylene octadecanoic acid. cis-3,4-Methylene hexanedioic acid and related compounds.

(1979)

Cytowania: 3Open AccessDOI ↗PubMed ↗PDF ↗

Solid−Liquid Equilibria for Hexanedioic Acid + Benzoic Acid, Benzoic Acid + Pentanedioic Acid, and Hexanedioic Acid + Pentanedioic Acid

Tzu-Chi Wang, Tzu-Yu Lai, Yan-Ping Chen (2010) · Journal of Chemical & Engineering Data

Cytowania: 17$ PaywallDOI ↗

Formation of n-hexanedioic acid from hexadecanoic acid by an initial ω oxidation in ketotic rats

Jon Elling Pettersen (1972) · Clinica Chimica Acta

Cytowania: 59$ PaywallDOI ↗

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Antimicrobial Constituents from Root

Jung-Eun Kim, Ji-Hye Seo, Min-Suk Bae et al. (2016) · Natural Product Communications

Cytowania: 11Open AccessDOI ↗PDF ↗

Hexanedioic acid

(2007) · Encyclopedic Dictionary of Polymers

$ PaywallDOI ↗

Hexanedioic Acid, Ammonium Salt 19090‐60‐9