Does BMA mean n-butyl methacrylate or isobutyl methacrylate?

In most commercial usage the bare abbreviation means the normal isomer, n-butyl methacrylate, CAS 97-88-1. The branched isomer, isobutyl methacrylate, is a different substance with its own identifiers and a different contribution to copolymer hardness, and the tertiary isomer is different again. Because all three are abbreviated loosely in day-to-day correspondence, an order written as BMA alone is ambiguous. Write the full chemical name and the CAS number on every enquiry, purchase order and goods-inwards record.

Why must the monomer not be blanketed with pure nitrogen?

Because the stabiliser used in commercial methacrylate monomers requires dissolved oxygen to function. It intercepts radicals by a mechanism that consumes oxygen, so a drum stripped of oxygen contains an inhibitor that is chemically present and functionally absent. The correct headspace is air, or air diluted with nitrogen to a specified oxygen content, never an inert blanket. This is one of the very few cases in a chemical store where displacing oxygen makes a material more dangerous rather than less, and it catches people whose instinct is trained on flammable solvents.

How should inhibitor content be read on a certificate?

As a starting condition rather than a permanent property. The certificate reports the inhibitor level at release; that level falls in storage as the stabiliser does its job, and it falls faster in warm conditions, in light and in the presence of contamination. A long-stored drum can meet its original certificate on every other line while having very little inhibitor left. Where storage has been long or uncertain, retest the inhibitor level before charging a reactor rather than relying on the release figure.

What is popcorn polymerisation and why does it matter here?

It is a self-propagating, expanding polymer growth that forms in dead legs, vapour spaces, valve bonnets and residues where inhibitor cannot reach. Once seeded it continues under conditions that would not start a normal polymerisation, and it grows mechanically enough to jam valves and distort equipment. The controls are housekeeping controls: no unswept dead legs, no long-standing residues, no lines left full between campaigns, and clean vessels before refilling. It is not a reason to avoid methacrylate monomers, but it is a reason to design the pipework as if the monomer were reactive, because it is.

How does the butyl ester change a copolymer compared with the methyl one?

The four-carbon ester side chain is flexible and bulky, so it loosens chain packing and lowers the temperature at which the polymer softens. Against the methyl ester it gives a softer, more flexible and more extensible polymer, better adhesion and easier film formation, at the cost of hardness and block resistance. Against the corresponding acrylate it gives a harder polymer with the weathering advantage of the methacrylate backbone. Formulators use it as the soft component of an all-methacrylate system, which keeps the durability while tuning flexibility.

Was ist Diethylene glycol dimethyl ether?

Diethylene glycol dimethyl ether ist eine chemische Verbindung, registriert unter der CAS-Nummer 110-71-4. Summenformel: C4H10O2. Molmasse: 90.12 g/mol. IUPAC: 1,2-dimethoxyethane.

Wie lautet die CAS-Nummer von Diethylene glycol dimethyl ether?

Die CAS-Nummer von Diethylene glycol dimethyl ether ist 110-71-4 — eine eindeutige Kennung des Chemical Abstracts Service (CAS).

Wie lautet die Summenformel von Diethylene glycol dimethyl ether?

Summenformel: C4H10O2. Molmasse: 90.12 g/mol. logP (XLogP3): -0.2. PSA: 18.5 Å².

Welche GHS-Gefahren hat Diethylene glycol dimethyl ether?

Gemäß der GHS-Klassifizierung muss Diethylene glycol dimethyl ether mit den folgenden Gefahrenhinweisen gekennzeichnet werden: H225 (Flüssigkeit und Dampf leicht entzündbar.), H360FD (Kann die Fruchtbarkeit beeinträchtigen. Kann das Kind im Mutterleib schädigen.), H332 (Gesundheitsschädlich bei Einatmen.), EUH019 (Kann explosionsfähige Peroxide bilden.).

Wo kann ich Diethylene glycol dimethyl ether kaufen?

Diethylene glycol dimethyl ether ist in unserem Shop erhältlich. Produkt ansehen: https://epchems.online/products/12-dimethoxyethane/

Woher stammen die chemischen Daten für Diethylene glycol dimethyl ether?

Die chemischen Daten für Diethylene glycol dimethyl ether stammen aus zuverlässigen Quellen: PubChem (NIH), ChEMBL (EBI). PubChem CID: 8071. Konform mit der CLP-Verordnung (EG 1272/2008), verfügbar unter der Lizenz CC-BY 4.0.

Diethylene glycol dimethyl ether

1,2-Dimethoxyethane

CAS 110-71-4 · C₄H₁₀O₂ · MW 90.12 g/mol

Über Diethylene glycol dimethyl ether

Diethylene glycol dimethyl ether ist eine chemische Verbindung, registriert unter der Nummer CAS 110-71-4, mit der Summenformel C₄H₁₀O₂, und einer Molmasse von 90.12 g/mol.

Das Molekül enthält 16 Atome, verbunden durch 15 chemische Bindungen. Der vollständige systematische IUPAC-Name dieser Verbindung lautet 1,2-dimethoxyethane. Das interaktive 3D-Modell oben zeigt die räumliche Anordnung der Atome — Sie können es mit der Maus drehen, mit dem Scrollrad zoomen und zwischen den Darstellungsmodi Skelett / Ball & Stick / Space Fill wechseln.

Hinsichtlich der physikalisch-chemischen Eigenschaften der Verteilungskoeffizient logP = -0.2 (negativer Wert, hydrophile Verbindung), polare Oberfläche PSA = 18.5 Å², 0 Donatoren und 2 Wasserstoffbrücken-Akzeptoren. Diese Parameter sind entscheidend für die Beurteilung der Bioverfügbarkeit und der Wechselwirkung mit Biomolekülen.

Die chemischen Daten für diese Verbindung stammen aus PubChem (NIH NLM NCBI), einer der größten chemischen Datenbanken der Welt. Alle Informationen werden automatisch aktualisiert und um GHS-Gefahrenhinweise gemäß der CLP-Verordnung (EG 1272/2008) ergänzt. Das obige Widget darf für Bildungs-, Forschungs- und kommerzielle Zwecke verwendet werden.

Physikalisch-chemische Eigenschaften

Wzór sumaryczny	C₄H₁₀O₂
Masa molowa	90.12 g/mol
IUPAC	1,2-dimethoxyethane
SMILES	`COCCOC`
InChIKey	`XTHFKEDIFFGKHM-UHFFFAOYSA-N`
logP (XLogP3)	-0.2
PSA	18.5 Å²
HBD / HBA	0 / 2
PubChem CID	CID 8071 ↗

GHS-Sicherheit

Sygnał: Niebezpieczeństwo

GHS02

GHS07

GHS08

H225 — Wysoce łatwopalna ciecz i pary

? — H360FD

H332 — Działa szkodliwie w następstwie wdychania

EUH019 — Może tworzyć nadtlenki o właściwościach wybuchowych

Wissenschaftliche Literatur

Literatura naukowa

20 artykułów · 11 open access · Źródła: PubMed, OpenAlex, Semantic Scholar

📈 Timeline publikacji (20 artykułów)

Wysokość słupka = liczba artykułów w roku. Hover dla szczegółów.

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Lithium phenolates solvated by tetrahydrofuran and 1,2-dimethoxyethane: structure determination using the method of continuous variation.

et al. (2009)

Cytowania: 26Open AccessDOI ↗PubMed ↗PDF ↗

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Influence of a Lewis acid and a Brønsted acid on the conversion of microcrystalline cellulose into 5-hydroxymethylfurfural in a single-phase reaction system of water and 1,2-dimethoxyethane.

et al. (2018)

Cytowania: 16Open AccessDOI ↗PubMed ↗PDF ↗

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Electrochemical behavior and electrodeposition of gallium in 1,2-dimethoxyethane-based electrolytes.

et al. (2021)

Cytowania: 3Open AccessDOI ↗PubMed ↗PDF ↗

Efficient synthesis of octyl-β-d-galactopyranoside by Bacillus spore-displayed β-galactosidase using an amphiphilic 1,2-dimethoxyethane co-solvent.

(2011)

Cytowania: 6$ PaywallDOI ↗PubMed ↗

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Bis(1,2-dimethoxyethane)-1κ(2)O,O';3κ(2)O,O'-tetra-kis-(μ-1,1,1,3,3,3-hexa-fluoro-2-methyl-propan-2-olato)-1:2κ(4)O:O;2:3κ(4)O:O-1,3-dilithium-2-magnesium.

(2012)

Cytowania: 2Open AccessDOI ↗PubMed ↗PDF ↗

Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum(IV) chloride and tungsten(IV) chloride.

et al. (2022)

Cytowania: 4$ PaywallDOI ↗PubMed ↗

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PHASE BEHAVIOUR CALCULATIONS FOR THE CARBON DIOXIDE + 1,2-DIMETHOXYETHANE BINARY SYSTEM WITH A CUBIC EQUATION OF STATE

Sergiu SIMA, Radu C. RACOVIŢĂ, Aurel CHIRILĂ et al. (2019) · Studia Universitatis Babes-Bolyai Chemia

Cytowania: 1Open AccessDOI ↗PDF ↗

Analysis of Cooperativity and Group Additivity in the Hydration of 1,2-Dimethoxyethane.

(2021)

Cytowania: 3$ PaywallDOI ↗PubMed ↗

Synthesis of Tris(1,2-dimethoxyethane-O,O')barium Bis(2,2,5,5-tetramethyl-2,5-disilaphospholanide) and the Monomer-Dimer Equilibrium in Toluene Solution.

(1996)

Cytowania: 9$ PaywallDOI ↗PubMed ↗

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Isobaric-isothermal molecular dynamics computer simulations of the properties of water-1,2-dimethoxyethane model mixtures

J. Gujt, H. Dominguez, S. Sokolowski et al. (2017) · arXiv (1710.01204v1)

Open AccessDOI ↗PDF ↗

Why is poly(oxyethylene) soluble in water? Evidence from the thermodynamic profile of the conformational equilibria of 1,2-dimethoxyethane and dimethoxymethane revealed by Raman spectroscopy.

(2014)

Cytowania: 16$ PaywallDOI ↗PubMed ↗

Analogy of the coordination chemistry of alkaline earth metal and lanthanide Ln(2+) ions: the isostructural zoo of mixed metal cages [IM(OtBu)4{Li(thf)}4(OH)] (M=Ca, Sr, Ba, Eu), [MM'6(OPh)8(thf)6] (M=Ca, Sr, Ba, Sm, Eu, M'=Li, Na), and their derivatives with 1,2-dimethoxyethane.

(2007)

Cytowania: 14$ PaywallDOI ↗PubMed ↗

A rare tetranuclear thorium(IV) μ4 -oxo cluster and dinuclear thorium(IV) complex assembled by carbon-oxygen bond activation of 1,2-dimethoxyethane (DME).

(2014)

Cytowania: 13$ PaywallDOI ↗PubMed ↗

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Revisiting Fluorobenzene as Diluents in Ether-Based Electrolytes for Lithium Metal Batteries

Hongji Pan, Tiantian Wang, Yanxin Jiang et al. (2025) · Nature Communications

Cytowania: 2Open AccessDOI ↗PDF ↗

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{5,15-Bis[3,5-bis(6′-methyl-2,2′-bipyridyl-6-yl)phenyl]-10,20-diphenylporphyrin}zinc(II) 1,2-dimethoxyethane 0.296-solvate

Aguri Akitomi, Yuta Kato, Yosuke Hosoya et al. (2026) · IUCrData

Open AccessDOI ↗PDF ↗

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Crystal structure of (dibenzo-21-crown-7)diiodidosamarium(II) 1,2-dimethoxyethane hemisolvate

Hannah B. Wineinger, Joseph M. Sperling, Thomas E. Albrecht (2026) · Acta Crystallographica Section E: Crystallographic Communications

Open AccessDOI ↗PDF ↗

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Solvation effect on conformations of 1,2:dimethoxyethane: charge-dependent nonlinear response in implicit solvent models.

(2008)

Cytowania: 32Open AccessDOI ↗PubMed ↗PDF ↗

Conductivities of 1,2-dimethoxyethane or 1,2-dimethoxyethane-related solutions of lithium salts

M. Yoshio, H. Nakamura, M. Hyakutake et al. (1993) · Journal of Power Sources

Cytowania: 13$ PaywallDOI ↗

The crystal and molecular structure of dibromo-bis(1,2 dimethoxyethane) titanium(III), tetrabromo(1,2-dimethoxyethane) titanate(III)

G.W.A. Fowles, T.E. Lester, J.S. Wood (1969) · Journal of Inorganic and Nuclear Chemistry

Cytowania: 12$ PaywallDOI ↗

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Bis(1,2-dimethoxyethane)-1κ(2)O,O';3κ(2)O,O'-tetra-kis-(μ-1,1,1,3,3,3-hexa-fluoro-2-methyl-propan-2-olato)-1:2κ(4)O:O;2:3κ(4)O:O-1,3-dilithium-2-magnesium.

Wurst K, Buchmeiser MR (2012) · Acta crystallographica. Section E, Structure reports online

Open AccessDOI ↗PubMed ↗PDF ↗

Dane z PubMed (NIH NLM), OpenAlex (CC0), Semantic Scholar (AI2). AI Summary wygenerowane przez Semantic Scholar TLDR. Artykuły z ikoną wymagają płatnego dostępu.

Synonyme

1,2-DIMETHOXYETHANE · 110-71-4 · Monoglyme · Ethylene glycol dimethyl ether · Glyme · Dimethyl Cellosolve · Dimethoxyethane · Egdme · 2,5-Dioxahexane · Ethane, 1,2-dimethoxy- · Glycol dimethyl ether · Dimethylcellosolve · Hisolve MMM · Ethylene dimethyl ether · Ansul ether 121

Datenquellen

📊 PubChem CID 8071 — NIH
🔬 NIST WebBook — spektroskopia
💊 ChEMBL — bioaktywność

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